Bad smell from heater

This is for a 2003 mitsubishi diamante. I have a really bad burning smell coming from my vents in my car it starts as soon as I start the car. Its not burning oil! I have been told it smells like burning electrical or burning antifreeze. So I was planning on changing out my heater core?? has anyone had this problem before?? This is my first car and i need it to commute to work please help!!!
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Comments
What kind of Mitsu? Year?
I think I'd want to narrow the problem down before replacing parts, much less the heater core. That's usually a big job, lots of labor on most cars.
Doesn't sound like it's mold or mildew that you are smelling though.
You might want to pressurize the cooling system with a pressure pump and see what turns up in terms of leaks. It doesn't take much of a leak to stink up a car.
So what's your plan now?