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Engine Oil--A slippery subject

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  • KCRamKCRam Member Posts: 3,516
    Shift,

    I wasn't referring to the radical flush as you describe; rather, the more basic kind you add to the oil before draining. The pump-flush you mention is great as part of a heavy-duty service along with an upper engine treatment (carbon cleaning).
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    yes I know you weren't kcram, thank you...I just threw that in there, since some people get confused about the terms.
  • lwflwf Member Posts: 223
    I haven't seen comments in anywhere in these Edmunds pages about the engine oil developed by WORLDWIDE PETROMOLY Inc., but an EPA report based on an 11-month investigation appears to have been pretty positive. PetroMoly's use provided increased fuel economy and decreased emissions (the motivation for its development). It contains soluble molecules of molybdenem disulfide (moly) which acts as a lubricant by filling the microscopic holes in the engine's cylinder walls, rings and pistons. I got the impression from the article I read that this "moly" is not just something that can be simply added to any brand of oil; rather, its blended in during production with a patented technology. With metal-to-metal contact virtually eliminated, PetroMoly oil is supposed to be good for 15,000 miles……..five times longer than conventional motor oils, and I think there is an implication that using this product will also greatly extend the life of the engine.

    Has anyone had experience with this product? Is it as good as it sounds? Is this a major breakthrough or just another after-market auto product that is very slippery, but not quite as much as the hucksters who sell it?
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    The science as quoted makes no sense whatsoever to me, lwf, it seems like the same old snake oil rap to me. Engine parts do not ride on each other, there is a film of oil between them, so what does "filling" the holes in pistons and cylinders (presuming a liquid could even do this) have to do with it? What can be slipperier than oil, and how much so? There's never "metal to metal" contact in an engine anyway (well, not for long!), so I don't see how it could be decreased. See what I mean? It brings up more questions than it answers?

    But if you have any more info, I'd like to examine it. thanks for posting, I wasn't trying to kill the messenger...:)
  • C13C13 Member Posts: 390
    Wouldn't that be a great name for a new line of motor oil?
  • KCRamKCRam Member Posts: 3,516
    C13,

    Better yet, I always wanted to start a company of all kinds of products called "The Leading Brand" - after all, that's who everyone compares to :)
  • lwflwf Member Posts: 223
    It's not much of an article, but see Business Week, 2/22/99 page 147. And there was no offense taken Mr. Shiftright. As indicated above, I'm skeptical also. What caught my eye was that the EPA allegedly published the favorable report. Nothing like having the US government tooting a private company's horn.
  • C13C13 Member Posts: 390
    It usually means they've contributed to somebody's campaign.

    Just kidding.
  • markbuckmarkbuck Member Posts: 1,021
    Ya'll remember Atlantic Richfield's moly oil back in the late 70's. Maybe it's being resurrected by PetroMoly.....

    Did a science fair project on ARCO's moly oil, run in 3.5 hp Briggs and Stratton's. Results were inconclusive but I was just a pup and believed alot of what I read back then.

    MolyDisulfide makes great assembly lube but as Mr_shiftright says their is supposed to be a hydrodynamic oil layer there anyway.
  • guitarzanguitarzan Member Posts: 873
    The key to THOSE tests is that a B&S engine will run for a good long time without ANY oil. Trust me, I have previously neglected our lawn tractor.
  • C13C13 Member Posts: 390
    I'm surprised GM doesn't enter into a partnership with B&S and advertise that their engines can run without oil.
  • rdeschenerdeschene Member Posts: 331
    To the best of my knowledge, Molybdenum Disulfide has been used in many "mainstream" motocross engines, and transmission fluids for quite some time now. So this isn't REALLY novel.

    I recall one of my chemistry profs using MbS2 as an example of a a molecule with a high ionic bond strength (here Mb-S), and how this can be used to advantage. In this case, the MbS2 molecule is very small (three atoms across, obviously) and approximately hexagonal.

    As a result, the outer-shell electrons on the MbS2 hydrogen-bond to iron atoms of the metal surface, and form and "interlocking grid" of these hexagonal molecules over the surface of the metal. Consequently, there is a layer of MbS2 on one metal surface rubbing against the MbS2 layer on the other surface. Unlike oil, where the oil stays on the surface through surface tension and viscosity alone, the MbS2 is hydrogen-bonded to the surface. This can still be removed, it just requires much more force to do so.

    Sorry if I've used more chemistry terms than most people are familiar with, but it's pretty standard, high school level chemistry. So it should still be pretty accessible.

    My (?) mark here, is more a matter of: are they able to keep any excess or "scrapped off" MbS2 suspended and flowing through the system? That is the problem with Teflon I believe. Is the level of anti-oxidant added adequate - as MbS2 on its own can be quite corrosive to steel. At least the EPA used a control!!! I'll give them that much.
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    Thanks for the science lesson! Well, the question is then whether this bonding means diddley to the overhaul picture inside the engine...does it make it slipperier than oil and by what % if so...or does it take longer to break down the oil film under duress? How much longer under how much more duress? Or more to the point...do the conditions under which it 'does it's thing' have any benefit in the real world that car engines operate in for the average driver?

    Controls, I like controls...when I was comparing the benefits of synthetic oils to regular oil in my car, first i collected the stats with regular, then with synthetic, and then i switched back to regular oil. Seems that last "control" made me realize that with improved maintenance and attention to driving, I had 'improved' the results with synthetic and kept most of them when i switched back to regular oil! (correct tire pressure, more attentive driving, wheel alignment, etc.)...nonetheless, even after the "control", the synthetic did offer faster warmups and slightly better fuel mileage.....worth the extra $17.50 at oil change time? Probably...

    Personally, I'm still prepared to drink any add to your oil additive (online videocam to record the results) that "substantially" improved fuel mileage, engine longevity, etc....
  • lwflwf Member Posts: 223
    I doubt if you'll ever get an answer rdeschene, but I'd like to read it if you do. By the way, I think your explanation in post 63 was quite good.
    Much better than the explanation in the BW article, and your question regarding possible engine corrosion definitely needs an answer. But if Molybdenum Disulfide has been used in motocross engines and been in transmission fluids for awhile, there should be information on this aspect of it. Probably doesn't cause corrosion. It's a little hard to believe a chemist would recommend a corrosive agent to be put in an engine to stay in it for 15,000 miles before replacement.

    Anyway, from what you explained, it's not a question of one oil being "slipperier" than another; its the metal-surface-protection processes that are different....hydrogen-bonded molecules rather than relying on surface tension and viscosity as is the case for conventional engine oil.

    Frankly, this idea of looking for a better oil brings to mind the old question of "if it ain't broke why fix it? Conventional engine oil seems to me to be pretty good. My last pickup had 140,000 miles on it when I got rid of it. I never had to add oil between changes, and the engine's compression was good the last time I had checked it at about 130,000. But I only asked about the Molybdenum Disulfide because I hadn't heard of the stuff before.
  • quadrunner500quadrunner500 Member Posts: 2,721
    Hold on there, maybe those synthetics haven't been widely accepted by automobile owners, but they are standard fare of the aviation engines since the 1940's. That may say something too.

    As for the BMW engine tests, I can say that I have seen electrical parts that carry a rating like 300,000 hours mean time between failures (MTBF). Since the part itself usually has not been in production for 34 years, obviously they are predicting results, not measuring them.
  • lwflwf Member Posts: 223
    Synthetic oil was standard for aviation engines in the 1940s? I don't think so. I was there from 1951 to 1955, and I never saw it go into the oil tanks of the R4360s I serviced and maintained.
  • quadrunner500quadrunner500 Member Posts: 2,721
    If my medication has affected my judgement about synthetic oils and aviation, I apologize. I thought synthetics were used in aviation applications first. As for the hydrogen bonded molecules, is that what the process 'ion implantation' is about? As for molybdenum, I believe it is added to steel for strength. It is an extreme pressure additive used in grease also.
  • poconojoepoconojoe Member Posts: 42
    Oil additives are the modern snake oil. My 93 Eagle summit got nothing but Walmart Tech 2000 oil( 74 cent qt.), changed every 3K. No problems for 224,000 mi.& still running.
  • markbuckmarkbuck Member Posts: 1,021
    Amen, poconojoe on the snake oil comment #71. I'm gonna go way upscale on my new Silverado and run Walmarts Tech 2000 synthetic blend. It retails for a whopping $1.20 or so a quart in gallon jugs.

    I do run full synthetics in my race bikes though.....they spend most of their time WFO near redline and oil costs are pretty much insignificant.
  • rdeschenerdeschene Member Posts: 331
    Quadrunner.

    RE: 'ion implantation'

    I've never heard the term before. I honestly have no idea what it means.

    You're quite right though, with respect to molybdenum being used in high pressure greases. I don't know if it's still around, or what my father used it for, but I remember a can of "moly-slip" he used to have.

    With respect to the corrosiveness of molybdenum, it can indeed be compensated for by (still other) additives. It's just one of those things that makes me apprehensive.

    The point about the 140,000 mile pickup is well taken though. That's why I e-mailed Mobil about a control group that used conventional oil. The person, who I know personally, with the highest mileage vehicle is a lady who has used nothing but Valvoline 10W30 in her (previous model) 4cyl. Mustang. The last time we spoke she had 220 ,000 miles on it.
  • edwardh1edwardh1 Member Posts: 88
    what weight oil is used in the northern parts of the us in winter?
  • markbuckmarkbuck Member Posts: 1,021
    what vehicle, year, motor, coldest temp expected, warmest temp expected?

    Most new vehicles are 5W-30..........
  • arjay1arjay1 Member Posts: 172
    I use a synthetic blend oil from Schaeffer Mfg. that contains "Moly". Check out their web site at WWW.Schaefferoil.com. They do not sell the product through retail outlets, they sell to big fleet users. You may be able to get it directly though, check on the web site. The benefit of this oil is that the base stock is so good they can put in more additives which provides a better product (the theory behind all synthetic oils). I use Supreme 7000 15W-40 all year in all my vehicles (live in Missouri). I change my oil every 10,000 miles and have run a diesel Mercedes to over 400,000 miles with no problems. I have sent my used oil for analysis and it shows very low levels of wear materials even at these extended drain intervals. I am sold on this product and it is not much more expensive then regular oil (about $30 per case).
  • ylockheadylockhead Member Posts: 10
    This may sound strange but what exactly is the difference between a 77 cent quart of oil and a premium oil like Castrol GTX? I always thought that the main difference was not the oil itself but the additives that are blended in the oil. After all, the 77 cent oil probably comes from the same refinery as the more expensive oil. I know for a fact that Imperial Oil oil is sold under many different brand names. So the only difference would seem to be the quality (or quantity) of the additives. Maybe the marketing cost of a brand name accounts for the higher price. Anybody care to comment on this...
  • rdeschenerdeschene Member Posts: 331
    edwardh1. I grew up in North Bay, Ontario and currently live in Brockville (city of the 1000 islands, quite nice if unexciting). The vast majority of people I know use the conventional oil recommended by the manufacturer.

    The only exceptions I know of personally, are people like me who use synthetic in the winter for easier turning over. It is quite noticeably better. A couple people I know do use STP or 15w40, but they have bearing problems in older cars that they are trying to keep going "just a bit longer".

    In North Bay, Timmins, etc. people use block heaters religiously and there's plug-ins at each parking spot at factories, apartments, etc.. That goes a LONG WAY to helping a car start-up when it's -20 or -40 deg.C
  • DropTop90DropTop90 Member Posts: 22
    The main reason I'm considering synthetic oil is my turbocharger. After the car is shut off, heat builds up inside the turbo which could cause "coking" or burning of the engine oil inside the turbo itself. Since synthetic oils can withstand temperature extremes, wouldn't they be more advantageous to use in cars with turbos? Anyone have any experience and/or knowledge on this?
  • KCRamKCRam Member Posts: 3,516
    DropTop,

    I currently own a turbodiesel, and my dad had an 88 Thunderbird Turbo for 5 years, so I'm very familiar with oil and blowers.

    You are correct that a synthetic can withstand heat better, but remember, once the engine is shut off, the oil is no longer moving. It will burn that much faster as it sits still. The secret to not coking your oil in a turbo is to let it cool down before shutting off the engine. The flowing oil will dissipate the heat through the rest of the engine. Most big rigs have exhaust temperature gauges - this allows the driver to know when he/she can shut down. Your owner's manual will usually recommend anywhere from 45 seconds to 2 minutes of cool-down idle depending on how long you were just on the road and what kind of driving y9u did.

    Even dinosaur juice will stay clean and clear if you keep your turbo's temp down before you turn it off. I stick with regular (natural) oil, and I don't even burn a quart between 5000 mile oil changes.

    And most important, if you're in that awful 60s habit of revving the engine as you turn off the key (my dad claimed it was to make sure you had a full complement of voltage), break that habit NOW. Revving a turbo as you turn the key simply spins it back up to boost pressure, wasting the cooldown completely.
  • shiposhipo Member Posts: 9,148
    During the 1980's, I had two Chrysler Turbo's, one with an intercooler (Turbo II) and one without (Turbo I). I used synthetic oil on both cars and drove each of them 80K+ miles. During that time, I never had any turbo problems. In contrast, my business partner and his wife had two Turbo I's both run on Dino Oil. Both cars needed new turbo-chargers around 50K miles.

    Obviously a four car sample does not mean too much, however, in my case the synthetic oil seemed to make a difference.

    Regards,
    Shipo
  • DropTop90DropTop90 Member Posts: 22
    I'm usually good with letting my car idle a bit before shutdown and I'm hoping that's good enough to prevent coking (some guys in my car club use turbo timers). Do either of you think it's worth the extra expense to use a synthetic for extra protection? Also, since I don't drive my car every day, would a synthetic really add a protective coating inside the engine? I'd think that most of the (dino) oil would drip into the crankcase after the car has been sitting for a couple of weeks. That concerns me.
  • markbuckmarkbuck Member Posts: 1,021
    Go synthetic for best turbo life, idle after high speed runs, but also make sure you purchase vehicles with turbochargers that circulate coolant through the turbo housing. When you shut down, the water will absorb a substantial amount of the residual heat allowing less oil baking. Most new designs include this, but many of the 70's and 80's turbo's relied on just oil, so when you shut down, the oil absorbed all of the heat, cooking the oil.....
  • KCRamKCRam Member Posts: 3,516
    shipo and mark,

    I put Valvoline Turbo V in my dad's Thunderbird almost exclusively - that could have been the difference. That was also a water-cooled turbo unit (IHI turbo as opposed to the Garretts that Chrysler used).

    My Cummins uses a Holset turbo, a company owned by Cummins. Valvoline also made natural oil specifically for Cummins under the brand name Premium Blue, also sold at Dodge dealers as Mopar Diesel Oil. My engine has seen nothing but that specific oil since new - now at 44,000 miles and no problems of any kind.

    DropTop,

    Synthetics only add coatings if they specifically say they will. Otherwise, they will actually drip back faster than dino, because they flow easier at any temperature. For a gasoline engine, I would recommend Castrol Syntec full-synthetic - it comes in 10W30 and 5W50.
  • shiposhipo Member Posts: 9,148
    Back in 1983 or so when I first heard about the (then) forth coming Chrysler 2.2 Turbo charged engines, I think I read somewhere that Chrysler actually holds the patent on the water cooled turbine bearing. Obviously that was 16 years ago so I may well have confused that fact with something else.

    However, I believe that all of Chrysler's 2.2 and 2.5 liter Turbos had the water cooled bearing.

    Regards,
    Shipo
  • markbuckmarkbuck Member Posts: 1,021
    Cummins blue is great! It is now available at my local Checker dealer as Valvoline Blue - Same price as Rotella and Delvac. Mobil does make a full synthetic marketed as Delvac 1. Ever consider trying it? - my old ford 7.3L started better on it when I went to ski areas in CO where I couldn't plug in.
  • KCRamKCRam Member Posts: 3,516
    luckily, NJ is only victim to an occasional cold snap - no extended zero/subzero temps, so the Valvoline is just fine - never burn any between oil changes, either.
  • DropTop90DropTop90 Member Posts: 22
    What about oil additives? There are a few on the market that claim to enhance standard engine oil. Any experiences, opinions or recommendations?
  • div2div2 Member Posts: 2,580
    DropTop90,
    A quality SJ rated oil will not require any additives. If you want to go all out for engine longevity and protection, use a synthetic(note that @90% of drivers and vehicles will be well seved by dino oil). Don't waste your money on snake oil.
  • DropTop90DropTop90 Member Posts: 22
    Makes sense. I change the oil every 3000-4000 miles. My car also has an engine oil cooler so the more I think about it, the less I'm considering the switch to synthetic.
  • quadrunner500quadrunner500 Member Posts: 2,721
    DropTop90,
    I think I hear your rods beginning to knock.
  • DropTop90DropTop90 Member Posts: 22
    Quadrunner500,
    With just 3500 miles on the odometer, I certainly hope not! I know a 210hp 4 cylinder has to work hard to keep me happy (and I plan to do at least one performance modification). An aquaintance with the same car uses a synthetic. That's why I'm here - to learn about the pros & cons so that I don't hear any knocking as the miles add up.
  • DropTop90DropTop90 Member Posts: 22
    I have a quart of Marvel Mystery Oil which is an engine oil additive. It claims to add a protective coating to moving parts, cleans the gum and gunk, all that good stuff. Opinions (on something other than the name)? Experiences?
  • larryslarrys Member Posts: 1
    Can you say "snake oil"?
  • KCRamKCRam Member Posts: 3,516
    most of these snake oils are the same additives that a premium motor oil will have anyway, just packaged separately. Outside of STP Oil Treatment, which is just extra detergents (always a good thing), you couldn't pay me enough to use snake oils.
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    I don't even think the extra detergents are worth anything, because they are not strong enough to 'clean' anything. At best, they are the same type of preventative detergent you find in your gasoline...and since preventative by definition has a law of diminishing returns (after a certain amount has performed a certain function, its useless, like too much flouride at each tooth-brushing....only so much can go to work, so to speak), you're probably wasting your money using a preventative detergent on top of a preventative detergent. To really clean gunk buildup in oil or fuel systems, you need industrial grade stuff, which is a) expensive and b) not sold over the counter in most stores.

    Change your oil, change your fuel filter, buy good products, and save your additive money for a nice lunch somewhere, that's my opinion.

    I'm now using synthetic in one of my high-strung Alfas, and I am pleased so far with the results, which are faster warm up and idle speed in cold weather, perhaps quieter valve/chain noise, and perhaps a little better fuel economy. I neither believe nor expect synthetic to prolong engine life to any measurable degree.
  • C13C13 Member Posts: 390
    How come every time I buy oil filters they're smaller than the last? Can you ask for the older big ones? Are generic filters as good as the brand name?
  • guitarzanguitarzan Member Posts: 873
    The one distinguishing factor I've seen is "paper backing". Many filters being sold are weak due to the use of cardboard inside. It is rare, but I've talked to enthusiasts who know people who've had filters collapse, or that were sucked into the oil pan. I would guess that this typically happens under extreme conditions, like high rev's, etc. But knowing that it has happened on average, everyday drivers is good enough reason for me to be concerned. For this reason, I use Bosch filters that have a "strong" metal backing.
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    I always buy OEM or the best filter I can find...I agree, I think there is a difference in quality, but you can't always tell looking at the box.
  • DropTop90DropTop90 Member Posts: 22
    Thanks for the snake oil input. The label on Marvel Mystery Oil says it can be added to either engine oil or gas and THAT's why the stuff is still unopened - guess I really wasn't sure what it was. I must have purchased it years ago to use in my Wrangler. Out it goes....
  • jj86jj86 Member Posts: 2
    I have a question. Durablend is a "synthetic blend." Anyone know how much synthetic oil is in it? Is it 50%? Or just 2 drops? I suppose 2 drops in each quart could be construed as a "blend." I changed from Mobil 1 to Durablend, but I wonder if that was a wise move.
  • clintonjohnclintonjohn Member Posts: 99
    I've heard that the blends are about 10% synthetic. When I found that out, I switched from blends at about $3/quart to buying one bottle of pure synthetic at around $4 and adding that to my four quart crankcase. Thus, for less money, I've got 25% synthetic oil in my car, rather than 10%. Also, from what I've read, it's 1. ok to self mix synthetic and regular oil, and 2. it's not harmful to mix different brands. So, I'll buy a quart of Mobil synthetic and pour it in with 3 quarts of Wal marts tech 2000 oil, which costs about .80/quart.
  • Mr_ShiftrightMr_Shiftright Member Posts: 64,481
    Marvel Mystery Oil is actually what they used to call an Upper Cylinder Lubricant. It's just a very light oil and that's why you can add it to gas, to coat the valve stems. Actually I think it's okay stuff to help free up an old engine sitting for some time, or perhaps a stuck lifter, but it's not going to perform any miracles beyond what any thin and high detergent oil can do.
This discussion has been closed.